2-{[4-(Dimethylamino)benzylidene]amino}phenyl disulfide

2-{[4-(Dimethyl­amino)­benzyl­idene]amino}­phenyl disulfide

In the title mol-ecule, C(30)H(30)N(4)S(2), the two benzene rings connected through the disulfide chain form a dihedral angle of 88.7 (1)°, and the two benzene rings in the benzyl-ideneaniline fragments form dihedral angles of 34.0 (1) and 35.4 (1)°. The crystal packing exhibits no significantly short inter-molecular contacts.

Bis(4-amino-2-chloro­phen­yl) disulfide

The title compound, C(12)H(10)Cl(2)N(2)S(2), features an S-S bond [2.0671 (16) Å] that bridges two 4-amino-2-chloro-phenyl rings with a C-S-S-C torsion angle of -84.2 (2)°. The two benzene rings are twisted with respect to each other at a dihedral angle of 39.9 (2)°. Inter-molecular N-H⋯S hydrogen bonding is present in the crystal structure.

Unprecedented metal-mediated in situ reactions of heterocyclic disulfide of di[4-(pyridin-2-yl)pyrimidinyl]disulfide.

By the combination of different metal salts and solvents, four unprecedented in situ reactions have been discovered for heterocyclic disulfide of 2-ppds (2-ppds = di[4-(pyridin-2-yl)pyrimidinyl]disulfide). In the CH3CN-DMF solvent, reaction of 2-ppds with AgNO3 produced a one-dimensional chain structure of {[Ag2(1L)2]·2CH3CN}n (1), wherein 2-ppds was converted into its sulfonate of 1L by means ...

Bis[2-(benzyl­idene­amino)­phen­yl] disulfide

In the title mol-ecule, C(26)H(20)N(2)S(2), the two benzene rings connected by a disulfide chain form a dihedral angle of 84.9 (1)°, and the two benzene rings in the two benzyl-idene-amino-phenyl fragments form dihedral angles of 34.4 (1) and 32.8 (1)°. The crystal structure exhibits weak inter-molecular C-H⋯S hydrogen bonds, which link the mol-ecules into chains along [101].

Disulfide Bond Oxidoreductase DsbA 2 of Legionella pneumophila 2 Exhibits Protein Disulfide Isomerase Activity 3